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Significantly, 40Ar/39Ar step-heating analyses resolve distinct age gradients for both FCT and ACR sanidine.Possible explanations for these gradients include combinations of recoil loss of 39Ar, instrumental bias, isotopic fractionation during step-heating, thermally induced argon loss and/or extraneous argon contamination.

Text is available under the CC BY-SA 4.0 license; additional terms may apply.2%; well outside the ±0.1% aspiration of EARTHTIME (Uncertainties in the ages of the K–Pg boundary and the Fish Canyon sanidine (FCs) Ar–Ar sanidine dating standard, and in the number and tuning of 405-kyr eccentricity-related cycles, hamper the construction of a reliable tuned time scale for the Palaeogene, a critical time period marked by the occurrence of hyperthermals and the onset of ice-house conditions.

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